Influence of Serratia marcescens on Carbon Steel Corrosion in Various Biodiesel Concentrations

IJEP 42(14): 1677-1685 : Vol. 42 Issue. 14 (Conference 2022)

Vivi A. Fardilah1, Yustina M. Pusparizkita2*, Wolfgang W. Schmahl3, Tjandra Setiadi4,5, Bork Ilsemann6, Mike Reich6, Hary Devianto4, Ardiyan Harimawan4 and Athanasius P. Bayuseno1*

1. Diponegoro University, Department of Mechanical Engineering, Faculty of Engineering,Tembalang 50275, Semarang, Central Java, Indonesia
2. Diponegoro University, Department of Environmental Engineering, Faculty of Engineering, Tembalang 50275, Semarang, Central Java, Indonesia
3. Ludwig Maximilian University Munich, Department of Earth and Environmental Sciences, Theresienstrasse 41, Munich 80333, Germany
4. Institut Teknologi Bandung, Department of Chemical Engineering, Faculty of Industrial Technology, Labtek X Jl. Ganesha, Bandung 40132, Indonesia
5. Bandung Institute of Technology, Center for Environmental Studies (PSLH), Jl. Sangkuriang 42 A, Bandung 40135, Indonesia
6. Ludwig Maximilian University of Munich, Paleontology and Geobiology, Department of Earth and Environmental Sciences, Richard-Wagner-Str. 10, Munich 80333, Germany

Abstract

Biodiesel is a renewable fuel derived from a mixture of hydrocarbons (diesel oil) with fatty acid methyl ester (FAME). However, its use as fuel sometimes causes problems since biodiesel is hygroscopic and can act as a carbon source for the metabolism of micro-organisms that cause steel corrosion. One species of micro-organism-induced corrosion (MIC) is Serratia marcescens. This study observed carbon steel ST-37 corrosion in the biodiesel mixture (B15, B20, B30) and contamination of S. marcescens. The effect of biodiesel concentration and MIC was investigated by electron impedance spectroscopy (EIS), scanning electron microscope (SEM) and digital microscope. The results showed that S. marcescens could form biofilm on carbon steel surfaces at various concentrations of biodiesel as medium. The phenomenon of MIC involvement was illustrated through the electrical equivalent circuit. Biofilm growth, pit depth and corrosion area were influenced by biodiesel concentration. The consequence of pitting corrosion affected metal surface roughness and strength.

Keywords

Corrosion, Pit, Biodiesel, Biofilm, Steel

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