Kinetic Modeling of Continuous Stirred Tank Reactor – Operating on Distillery Effluent

IJEP 42(6): 685-693 : Vol. 42 Issue. 6 (June 2022)

D. D. Mohite1, S. S. Salimath2* and V.V. Muthekar3

1. VTU Regional Research Centre, Belgavi – 590 018, Karnataka, India
2. Cambridge Institute of Technology, Bangaluru – 560 036, Karnataka, India
3. MIT Academy of Engineering, Alandi, Pune – 412 105, Maharashtra, India

Abstract

To identify the viability and performance, distillery effluent having very high organic content was studied on continuous stirred tank reactor (CSTR). Under different organic loading rates (OLR) and optimum conditions for highest chemical oxygen demand (COD) removal and biogas generation was found for OLR of 0.10-0.11 COD kg/day. Highest COD exertion efficiency was found to be around 73% for OLR of 9.166 kg COD/m3/day when hydraulic retention time (HRT) was reduced from 15 to 14 days. Biogas generation was observed to be around 30 L/day with a conversion coefficient of 0.405 and volatile fatty acids (VFA) to alkalinity ratio was recorded to be 0.12 in this stage. Applying the modified Stover Kincannon model to the reactor, the maximum removal rate constant (Umax) and saturation value constant (Kb) were found to be 17.123 kg/m3/day and 33.471 kg/m3/day, respectively. These records are predominantly significant when operating the anaerobic biodigesters fortreating the distillery effluent alongwith the production of biogas as an energy source. CSTR can effectively be employed in treatment of this effluent, however, post bio-digestion effluent still contains considerable COD. To meet the pollution norms and standards it needs to be treated further. To understand the complex biological treatment process of this effluent further trials are required to be conducted.

Keywords

Anaerobic continuous stirred tank reactor, Distillery effluent, Chemical oxygen demand, Biogas, Pollution, Stover Kincannon kinetic model

References

  1. Shankaran, K., et al. 2011. Analysis on biode-radation and colour reduction of distillery effluent spent wash. Asian J. Sci. Tech., 2(3):15-21.
  2. Chidanand, P., P. Kalbungi and M. Ghorpade. 2015. Performance and evaluation of sugar and distillery effluents treatment plant. Int. Res. J. Eng. Tech., 2(3):1456-1460.
  3. Tapas, N., S. Shastry and S. Kaul. 2002. Wastewater management in a cane molasses distillery involving bioresource recovery. J. Env. Manage., 65(1):25-38.
  4. Pankaj, C., K. Nawaz and R. Bhargava. 2018. Distillery wastewater: It’s impact on environment and anaerobic digestor: A review. Env. Analysis Ecol. Studies. 1(2):14-17.
  5. Satyawali, Y. and M. Balakrishnan. 2008. Wastewater treatment in molasses-based alcohol distilleries for COD and colour removal: A review. J. Int. Manage., 86(3):481-497.
  6. Dikshit, M. and S. Chauhan. 2012. Indian distillery industry: problems and prospects of decolo-urisation of spent wash. International Conference on Future environment and energy (IPCBEE). JACSIT Press, Singapore. Vol. 28.
  7. CPCB. 2017. Draft guidelines for co-processing of distillery spent wash-concrete in cement industries. Central Pollution Control Board, New Delhi.
  8. Sowmeyan, R. and G. Swaminathan. 2008. Effluent treatment process in molasses-based distillery industries: A review. J. Hazard. Mater., 152(2):2453-2462.
  9. Rajeshwari, K., et al. 2000. State-of-the-art of anaerobic digestion technology for industrial wastewater treatment. Renew. Sustain. Energy Reviews. 4(2):135-156.
  10. CPCB. 2015. Guidelines on techo-economic feasibility of implementation of zero liquid discharge for water pollution industries. Central Pollution Control Board, New Delhi.
  11. Ravikumar, R., et al. 2007. Biodegradation and decolourization of biomethanated distillery spent wash. Indian J. Sci. Tech., 1(2): 1-6.
  12. Moletta, R. 2005. Winery and distillery wastewater treatment by anaerobic digestion. Water Sci. Tech., 51(1):137-144.
  13. Mohite, D. and S. Salimath. 2019. Performance optimization of distillery spent wash in anaerobic hybrid reactor. Water Res., 41(4):721-730.
  14. Bhavik, K., M. Sarayu and D. Madamwar. 2008. Anaerobic treatment of distillery spent wash-A study on upflow anaerobic fixed film bioreactor. Bioresour. Tech., 99(11):4621-4626.
  15. Prakash, N., V. Sockam and V. Raju. 2014. Anaerobic digestion of distillery spent wash. APRN J. Sci. Tech., 4(3):2225-7217.
  16. Patel, H. and D. Madamwar. 2002. Effects of temperatures and organic loading rates on biome-thanation of acidic petrochemical wastewater using an anaerobic upflow fixed-film reactor. Bioresour. Tech., 82(1):65-71.
  17. APHA. 2005. Standard methods for the examination of water and wastewater (21st edn). American Public Health Association, Washington D.C.
  18. Gao, W., et al. 2011. Effects of temperature and temperature shock on the performance and microbial community structure of a submerged anaerobic membrane bioreactor. Bioresour. Tech., 102 (19): 8733-8740.
  19. Appels, L., et al. 2008. Principles and potential of the anaerobic digestion of waste-activated sludge. Progress Energy Combus. Sci., 34(6):755-781.
  20. Muzaffar, A., A. Hussain and C. Verma. 2016. Design considerations and operational performance of anaerobic digester: A review. Cogent Eng., 3(1).
  21. Chapleur, O., et al. 2016. Asymmetrical response of anaerobic digestion. Appl. Env. Microbiol., 100:1445-1457.
  22. Perez-Garcia, M., et al. 2005. Effect of the pH influent condition in fixed-film reactors for anaerobic thermopillic treatment of wine-distillery wastewater. Water Sci. Tech., 51(1):183-189.
  23. Bolzonellas, D., et al. 2005. Mesophelic anaerobic digestion of waste activated sludge influence of solid retention time in the wastewater treatment process. Process Biochem., 40:1453-1460.
  24. Benabdallah, T., J. Dosta and J. Mata-Alvarez. 2007. Start-up and HRT influence to thermophilic and mesophilic anaerobic digesters seeded with waste activated sludge. Chem. Biochem. Eng., 21(2):145-150.
  25. Gupta, S. and G. Singh. 2007. Biodegradation of distillery spent wash in anaerobic hybrid reactor. Waste Res., 41(4):721-730.
  26. Rajesh, J., et al. 2006. Treatment of spent wash in anaerobic mesophilic suspended growth reactor (AMSGR). J. Env. Biol., 27(1):111-117.
  27. Patel, H. 2000. Biomethanation of low pH petrochemical weastewater using up-flow fixed film anaerobic bioreactors. World J. Microbial. Biotech., 16(1):69-75.
  28. Bhavik, K., et al. 2011. Kinetic modelling and microbial community assessment of anaerobic biphasic fixed film bioreactor treating distillery spent wash. Water Res., 45(14):4248-4259.