IJEP 43(11): 963-971 : Vol. 43 Issue. 11 (November 2023)
G.K. Sendil1, M. Roselin Ranjitha2, E. Soundarrajan1, R.A. Kalaivani1* and S. Raghu3*
1. Vels Institute of Science, Technology and Advanced Studies (VISTAS), Department of Chemistry, Chennai – 600 117, Tamil Nadu, India
2. Stella Maris College (Autonomous), Department of Chemistry, Chennai – 600 086, Tamil Nadu, India
3. Vels Institute of Science, Technology and Advanced Studies (VISTAS), Centre for Advanced Research and Development (CARD), Chennai – 600 117, Tamil Nadu, India
Abstract
Deterioration of water resources and increased levels of water pollution have become two major factors that threaten the fundamental balance of ecosystems. Owed to their destructive impact, the concern to regulate and remediate them has amplified in the recent past. Herein we presently propose a simple hydrothermal strategy for synthesizing iron phosphate, FePO4 (FP) nanoparticles. Their ability as a photocatalyst material for photocatalytically degrading Reactive Black 5, Red 198 and Yellow 145 dyes was examined and found to be 95.74, 90.32 and 87.65%, respectively. The dependency of photocatalysis process on dye concentration and pH was explored to enlighten the possible variations that might occur during practical applications. Furthermore, the kinetic pathway in which the photocatalysis takes place was also verified to fall under pseudo-first order kinetics. Recyclability/reusability parameter was also studied to elaborate on its optimum efficiency when the photocatalyst is used repeatedly. In conclusion, the synthesized FP photocatalyst is demonstrated to act as a promising material for superior photocatalytic degradation of dyes in wastewater effluents.
Keywords
Iron phosphate, Hydrothermal synthesis, Photocatalysis, Reactive Black 5, Reactive Red 198, Reactive Yellow 145
References
- Yaseen, D.A. and M. Scholz. 2019. Textile dye wastewater characteristics and constituents of synthetic effluents: A critical review. Int. J. Env. Sci. Tech., 16(2):1193–1226. DOI: 10.1007/s13762-018-2130-z.
- Hassan, M.M. and C.M. Carr. 2018. A critical review on recent advancements of the removal of reactive dyes from dyehouse effluent by ion-exchange adsorbents. Chemosphere. 209:201–219. DOI: 10.1016 j.chemosphere.2018.06.043.
- Mishra, S. and A. Maiti. 2018. The efficacy of bacterial species to decolourise reactive azo, anthroquinone and triphenylmethane dyes from wastewater: A review. Env. Sci. Poll. Res., 25(9): 8286–8314. DOI: 10.1007/s11356-018-1273-2.
- Asgher, M. 2012. Biosorption of reactive dyes : A review. Water Air Soil Poll., 223 (5):2417–2435. DOI: 10.1007/s11270-011-1034-z.
- Rueda-Marquez, J.J. 2020. A critical review on application of photocatalysis for toxicity reduction of real wastewaters. J. Clean. Prod., 258. DOI: 10.1016/j.jclepro.2020.120694.
- Zhang, F., et al. 2019. Recent advances and applications of semiconductor photocatalytic technology. Appl. Sci., 9(12). DOI: 10.3390/app9122489.
- Anwer, H., et al. 2019. Photocatalysts for degradation of dyes in industrial effluents: Opportunities and challenges. Nano Res., 12(5):955–972. DOI: 10.1007/s12274-019-2287-0.
- Di Paola, A., et al. 2012. A survey of photocatalytic materials for environmental remediation. J. Hazard. Mater., 211–212:3–29. DOI: 10.1016/j.jhaz mat.2011.11.050.
- Sarkar, S., et al. 2020. Green polymeric nanoma-terials for the photocatalytic degradation of dyes: A review. Env. Chem. Lett., 18(5):1569–1580. DOI: 10311-020-01021-w.
- Lopes, J.L., et al. 2021. Carbon-based heterogeneous photocatalysts for water cleaning technologies: A review. Env. Chem. Lett., 19(1):643–668. DOI: 10.1007/s10311-020-01092-9.
- Paolella, A., et al. 2017. Light-assisted delithiation of lithium iron phosphate nanocrystals towards photo-rechargeable lithium ion batteries. Nat. Commun., 8:1–10. DOI: 10.1038/ncomms14643.
- Elsawy, H., et al. 2021. Synthesis and antimicrobial activity assessment of calcium and iron phosphate nanoparticles prepared by a facile and cost-effective method. Chem. Phys. Lett., 779(April): 138839. DOI: 10.1016/j.cplett.2021.138839.
- Zhang, X., et al. 2020. Structure, morphology, size and application of iron phosphate. Rev. Adv. Mater. Sci., 59(1):538–552. DOI: 10.1515/rams-2020-0039.
- Von Moos, L.M., et al. 2017. Iron phosphate nanoparticles for food fortification: Biological effects in rats and human cell lines. Nanotoxicol., 11 (4): 496–506. DOI: 10.1080/17435390.2017. 1314035.
- Liu, R. and D. Zhao. 2007. In-situ immobilization of Cu(II) in soils using a new class of iron phosphate nanoparticles. Chemosphere. 68(10):1867–1876. DOI: 10.1016/j.chemosphere.2007.03.010.
- El-Lateef, H.M.A., et al. 2019. Enhanced adsorption and removal of urea from aqueous solutions using eco-friendly iron phosphate nanoparticles. J. Env. Chem. Eng., 7(1):102939. DOI: 10.1016/j.je ce.2019.102939.
- Zhou, W., et al. 2009. Biosynthesis of iron phosphate nanopowders. Powder Tech., 194 (1–2): 106–108. DOI: 10.1016/j.powtec.2009.03.034.
- Liu, Y., et al. 2017. Synthesis of different structured FePO4for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural. RSC Adv., 7(81): 51281–51289. DOI: 10.1039/c7ra09 186a.
- Mathiarasu, R.R., et al. 2021. Hexagonal basalt, like ceramics LaxMg1-XTiO3(x=0 and 0.5) contrived via deep eutectic solvent for selective electrochemical detection of dopamine. Phys. B Condens. Matter., 615 (April):413068. DOI: 10.1016/j.physb.20 21.413068.
- Sendil, G.K., et al. 2023. Hydrothermal synthesis of copper-decorated titanium dioxide spherulites and their photocatalytic activity against reactive dyes. Asian J. Chem., 35 (1): 45–51.
- Mimouni, I., et al. 2022. Iron phosphate for photocatalytic removal of ibuprofen from aqueous media under sun-like irradiation. J. Photochem. Photobiol. Chem., 433 (March):114170. DOI: 10.1016/j.jpho tochem.2022.114170.
- Benomara, A., F. Guenfoud and M. Mokhtari. 2019. Removal of Methyl Violet 2B by FePO4as photocatalyst. React. Kinet. Mech. Catal., 127 (2):1087–1099. DOI: 10.1007/s11144-019-01607-8.
- Bentes, V.L.I., et al. 2021. Composite of iron phosphate-supported carbon from the Açaí (Euterpe oleracea) as a solid catalyst for photo-Fenton reactions. Env. Nanotech., Monit. Manage., 16 (July): 100520. DOI: 10.1016/j.enmm.2021.100520.
- Zhou, H., et al. 2018. Graphene oxide-FePO4nano-composite: Synthesis, characterization and photocatalytic properties as a Fenton-like catalyst. Ceram. Int., 44(6): 7240–7244. DOI: 10.1016/j.ce ramint.2018.01.176.
- Mathiarasu, R.R., et al. 2022. Reline deep eutectic solvent mediated synthesis of lanthanum titanate for heavy metal remediation and photocatalytic degradation. Chemosphere. 308(P3):136529. DOI: 10.1016/j.chemosphere.2022.136529.
- Zhang, X.X., et al. 2012. Iron phosphate as a novel sorbent for selective adsorption of chromium(III) and chromium speciation with detection by ETAAS. J. Anal. Atomic Spectrom. 27(3):466–472. DOI: 10.1039/c2ja10292g.
- Mathiarasu, R.R., et al. 2021. Photocatalytic degradation of reactive anionic dyes RB5, RR198 and RY145 via rare earth element (REE) lanthanum substituted CaTiO3perovskite catalysts. J. Mater. Res. Tech., 15:5936–5947. DOI: 10.1016/j.jmrt.2021. 11.047.
- Wang, C., et al. 2021. A novel strategy for enhancing heterogeneous Fenton degradation of dye wastewater using natural pyrite: Kinetics and mechanism. Chemosphere. 272:129883. DOI: 10.1016/j.chemosphere.2021.129883.